Atomistic Descriptions of Gas-Surface Interactions on Tin Dioxide
نویسندگان
چکیده
Historically, in gas sensing literature, the focus on “mechanisms” has been oxygen species chemisorbed (ionosorbed) from ambient atmosphere, but what these actually represent and location of adsorption site surface solid are typically not well described. Recent advances computational modelling experimental science provide insights likely mechanism by which other interact with SnO2, providing insight into future directions for materials design optimisation. This article reviews proposed models reaction including a summary conventional evidence ionosorption recent operando spectroscopy studies atomistic interactions surface. The analysis is extended to include common target interfering reducing gases, such as CO H2, cross-interactions H2O vapour, NO2 an example oxidising gas. We emphasise importance vacancies both preferred many gases self-doping SnO2.
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ژورنال
عنوان ژورنال: Chemosensors
سال: 2021
ISSN: ['2227-9040']
DOI: https://doi.org/10.3390/chemosensors9090270